Synthesis and Structure of (4-Acetyl-3-hydroxyphenoxy)tetraphenylantimony |
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| Authors: | Sharutin V. V. Sharutina O. K. Bondar' E. A. Subacheva O. V. Pakusina A. P. Gerasimenko A. V. Sergienko S. S. |
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| Affiliation: | (1) Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia |
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| Abstract: | Pentaphenylantimony was reacted with 4-acetyl-1,3-dihydroxybenzene in toluene at elevated temperature to obtain (4-acetyl-3-hydroxyphenoxy)tetraphenylantimony in 93% yield. According to X-ray diffraction data, the antimony atom in (4-acetyl-3-hydroxy-phenoxy)tetraphenylantimony has a distorted trigonal-bipyramidal configuration. The Sb-O and Sb-C distances are 2.237(1) and 2.112(1), 2.114(2), 2.118(2), 2.170(2) Å, respectively, and the CSbO angle is 177.86(5)°. |
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