Studies on sulfinatodehalogenation: The addition of polyfluoroalkyl iodides to olefins promoted by sodium bisulfite and sodium sulfite |
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| Authors: | Fanhong Wu Xueyan Yang Weiyuan Huang |
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| Affiliation: | a School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
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| Abstract: | The reaction of polyfluoroalkyl iodides with alkenes or 4-pentenoic acid promoted by sodium bisulfite or sodium sulfite in DMF aqueous solution was realized. The reaction of alkenes gave corresponding adducts, while γ-lactones were obtained in the case of 4-pentenoic acid in good yields. |
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| Keywords: | Polyfluoroalkylation Sodium bisulfite Sodium sulfite Addition reaction Lactonization |
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