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Synthesis of new pentafluorosulfanylacrylates (F5SCHCHCHO, F5SCHCHCN, F5SCHCHCOOCH3) and use of them as dienophiles in Diels-Alder reaction
Authors:Valery K Brel
Institution:Institute of Physiologically Active Compounds of Russian Academy of Science, Chernogolovka 142432, Moscow Region, Russia
Abstract:New pentafluoro-λ6-sulfanylacrylates (F5SCHdouble bond; length as m-dashCHCHO, F5SCHdouble bond; length as m-dashCHCN, F5SCHdouble bond; length as m-dashCHCOOCH3) were synthesized by a convenient and efficient method. These compounds are useful as intermediates in the preparation of pentafluoro-λ6-sulfanyl-containing cyclic and heterocyclic Diels-Alder cycloadducts.
Keywords:Alkenes  Diels-Alder  Fluorine  Sulfur
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