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Three-fold polyfluoroalkylated amines and isocyanates based on tris(hydroxymethyl)aminomethane (TRIS) |
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| Authors: | Robert Kaplá nek,Tomá &scaron B?í za,Martin Havlí k,Vladimí r Krá l |
| Affiliation: | a Department of Analytical Chemistry, Institute of Chemical Technology in Prague, Technická 5, 16628 Prague 6, Czech Republic b First Faculty of Medicine, Charles University in Prague, Kate?inská 32, 12108 Prague 2, Czech Republic |
| Abstract: | Three-fold polyfluoroalkylated amines were prepared from tris(hydroxymethyl)aminomethane (TRIS) in five steps including perfluoroalkyl iodide addition to the corresponding allyl derivative, reduction of C-I bond and deprotection of the amino group. They can be easily converted to the corresponding isocyanates. |
| Keywords: | Polyfluoroalkylated amine Polyfluoroalkylated isocyanate Nucleophilic fluorinated reagent Electrophilic fluorinated reagent Fluorous tag Fluorous building block Fluorinated dendron Polyfluoroalkylating agent TRIS |
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