A novel ytterbium/perfluoroalkylated-pyridine catalyst for Baylis-Hillman reaction in a fluorous biphasic system |
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Authors: | Wen-Bin Yi Chun Cai Xin Wang |
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Institution: | Chemical Engineering College, Nanjing University of Science & Technology, Nanjing 210094, China |
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Abstract: | Ytterbium perfluorooctanesulfonate Yb(OPf)3] catalyses the highly efficient Baylis-Hillman reaction in the presence of a catalytic amount of a novel perfluoroalkylated-pyridine as a ligand in a fluorous biphasic system (FBS) composed of toluene and perfluorodecalin. The new process can be carried out successfully without the use of a stoichiometric amount of Lewis base. The fluorous phase containing the active catalytic species is easily separated and can be reused several times without significant loss of catalytic activity. |
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Keywords: | Baylis-Hillman reaction Ytterbium perfluorooctanesulfonate Perfluorinated pyridine Fluorous biphasic catalysis |
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