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A well feasible and general route to (organoethynyl)difluoroboranes, RHCCBF2, and their perfluorinated analogues, RFCCBF2
Authors:Vadim V Bardin  Hermann-Josef Frohn
Institution:a N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrentjev Ave. 9, 630090 Novosibirsk, Russia
b Department of Chemistry, Inorganic Chemistry, University of Duisburg-Essen, Lotharstr. 1, D-47048 Duisburg, Germany
Abstract:A representative series of (organoethynyl)difluoroboranes RCtriple bond; length of mdashCBF2 (Rdouble bond; length as m-dashC4H9, (CH3)3C, CF3, C3F7, (CF3)2CF, CF3CFdouble bond; length as m-dashCF, C4F9CFdouble bond; length as m-dashCF, C6F5) was prepared by abstraction of fluoride from the corresponding KRCtriple bond; length of mdashCBF3] salts with BF3 in appropriate solvents (1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluorobutane, or dichloromethane).
Keywords:Fluoroboranes  Fluoroborates  Alk-1-ynylboron compounds  NMR spectroscopy
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