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Stereoselective synthesis of 4-fluoro-1,3-alkadienylboronates and their application in the stereoselective synthesis of fluoropolyenes
Authors:Miho Sakai
Affiliation:Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
Abstract:(1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-reaction of a vinylboronate with (E)- or (Z)-2-fluoro-1-alkenyliodonium salts, and applied to the Suzuki-Miyaura coupling reaction for the synthesis of fluoropolyenes.
Keywords:Heck-reaction   Fluoroalkadienylboronates   Suzuki-Miyaura coupling   Fluoropolyene   Fluoroalkenyliodonium salts
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