Stereoselective synthesis of 4-fluoro-1,3-alkadienylboronates and their application in the stereoselective synthesis of fluoropolyenes |
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Authors: | Miho Sakai |
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Affiliation: | Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan |
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Abstract: | (1E,3E)- and (1E,3Z)-4-fluoro-1,3-alkadienylboronates were stereoselectively prepared by the Heck-reaction of a vinylboronate with (E)- or (Z)-2-fluoro-1-alkenyliodonium salts, and applied to the Suzuki-Miyaura coupling reaction for the synthesis of fluoropolyenes. |
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Keywords: | Heck-reaction Fluoroalkadienylboronates Suzuki-Miyaura coupling Fluoropolyene Fluoroalkenyliodonium salts |
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