Fluoride-mediated selective cross-coupling reactions of alkyl halides and trimethyl(perfluoroalkyl)silanes, Me3SiRf (Rf = CF3, C2F5) in the absence of any catalysts期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Fluoride-mediated selective cross-coupling reactions of alkyl halides and trimethyl(perfluoroalkyl)silanes, Me₃SiR_f (R_f = CF₃, C₂F₅) in the absence of any catalysts

Authors:	Wieland Tyrra Dieter Naumann Sigrid Buslei Mikhail M. Kremlev

Affiliation:	^a Institut für Anorganische Chemie, Universität zu Köln, Greinstr. 6, D-50939 Köln, Germany ^b Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanskaya St. 5, UA-02094 Kiev, Ukraine

Abstract:	A temperature range of −18 °C to room temperature was found to be effective for selective fluoride-mediated cross-coupling reactions of trimethyl(perfluoroalkyl)silanes, Me₃SiCF₃ and Me₃SiC₂F₅, and alkyl halides, RX (X = Br, I) in the absence of any catalyst.

Keywords:	Trimethyl(trifluoromethyl)silane Trimethyl(pentafluoroethyl)silane Cross-coupling Fluoride
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