|
|||||
|
|
| 1-氨基-2-(2'-甲基-4'-丙酸甲酯)苯氧基-4-羟基蒽醌的合成 | |
| 引用本文： | 胡莹玉,李红斌,孙灵,沈永嘉,邱忠成.1-氨基-2-(2'-甲基-4'-丙酸甲酯)苯氧基-4-羟基蒽醌的合成[J].有机化学,2000,20(4):533-536. |
| 作者姓名： | 胡莹玉 李红斌 孙灵 沈永嘉 邱忠成 |
| 作者单位： | 1. 上海大学环境与建筑工程学院,上海,200072 2. 华东理工大学精细化工研究所,上海,200237 3. 上海分析仪器总厂,上海,200233 |
| 摘 要： | 邻甲苯酚与丙烯腈经Friedel-Crafts反应得到了2-甲基-4-β-氰基乙基苯酚，其与1-氨基-2-溴-4-羟基蒽醌经亲核取代形成的产物经水解、酯化得到目标化合物。给出了该化合物及其中间体的质谱、核磁共振氢谱、元素分析、可见光谱及熔点等数据。 |
| 关 键 词： | 丙酸酯 苯氧基 蒽醌P 苯酚P 丙烯腈 质谱法 质子磁共振谱法 元素分析 |
Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone |
|
| HU Ying-Yu,LI Hong-Bin,SUN Ling,SHEN Yong-Jia,QIU Zhong-Cheng.Synthesis of 1-amino-2-(2'-methyl-4'-methyl propionate) phenoxy-4- hydroxy anthraquinone[J].Chinese Journal of Organic Chemistry,2000,20(4):533-536. | |
| Authors: | HU Ying-Yu LI Hong-Bin SUN Ling SHEN Yong-Jia QIU Zhong-Cheng |
| Abstract: | 2 - Methyl - 4 - B - cyanoethylphenol was synthesized via Friedel - Crafts reaction between o - cresol and acrylonitrile. It was condensed with 1 - amino - 2 - bromo - 4 - hydroxy anthraquinone by the nucleophilic reaction. The product was hydrolyzed in alkaline medium and esterified with methanol to afford the title compound . Mass , H NMR, element analyses, Vis spectra and the melting points of the title compound and the intermediates were measured . |
| Keywords: | PROPIONATE PHENOXY GROUP ANTHRAQUINONE P PHENOL P ACRYLONITRILE MASS SPECTROGRAPHY PROTON MAGNETIC RESONANCE SPECTROMETRY ELEMENTAL ANALYSIS |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
| 点击此处可从《有机化学》浏览原始摘要信息 | |
| 点击此处可从《有机化学》下载免费的PDF全文 | |