Diels-Alder reaction of sugar-derived cyclic dienophiles with cyclopentadiene. Factors affecting the reactivity and stereoselectivity |
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| Authors: | Pellegrinet Spanevello |
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| Institution: | Instituto de Quimica Organica de Sintesis, Facultad de Ciencias Bioquimicas y Farmaceuticas, Universidad Nacional de Rosario-CONICET, Argentina. |
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| Abstract: | formula: see text] A sugar-derived cyclic dienophile showed a high exo and face selectivity in the Diels-Alder reaction with cyclopentadiene. Structural modifications on the dienophile structure were made, and the outcomes of the cycloaddition reactions were investigated. These results and the spectroscopic data recorded within a series of analogues were used to analyze the factors affecting the reactivity and exo selectivity. |
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