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Application of a novel lipophilized fluorescent dye in an optical nitrate sensor
Authors:Gerhard J Mohr  Tobias Werner and Otto S Wolfbeis
Institution:(1) Institute of Organic Chemistry, Analytical Division, Karl-Franzens University, Heinrichstr. 28, A-8010 Graz, Austria
Abstract:A new lipophilic pH probe (1-hydroxypyrene-3,6,8-tris-octadecylsulfonamide) has been synthesized, and its spectral properties and applications in a solid state nitrate sensor are shown. The sensor is investigated with respect to sensitivity, limits of detection, and selectivity over other anions found in drinking water.Abbreviations used HPTS trisodium-1-hydroxy-pyrene-3,6,8-trisul-fonate - HPTS-TO 1-hydroxypyrene-tris-3,6,8-octadecylsulfonamide - TDMACl tridodecylmethylammonium chloride - PVC poly(vinyl chloride) - DOS bis-(2-ethylhexyl)-sebacate - THF tetrahydrofurane - DMF dimethylformamide
Keywords:Lipophilic fluorescent dye  optical nitrate determination
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