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Trapping of Tricarbonyl(η1,η2‐homoallyl)iron and Tricarbonyl(η3‐allyl)iron Anion Intermediates with 2‐(Phenylsulfonyl)‐3‐phenyloxaziridine |
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| Authors: | Ming‐Chang P Yeh Jin‐Xuan Ho Peng‐Yu Hsueh |
| Abstract: | The addition of reactive carbanions to (η4‐1,3‐diene)Fe(CO)3 complexes at ?78 °C and 25 °C produced putative homoallyl and allyl anion complexes, respectively. Reaction of the reactive intermediates with 2‐(phenylsulfonyl)‐3‐phenyloxaziridine afforded nucleophilic substituted (η4‐1,3‐diene)Fe(CO)3 complexes. |
| Keywords: | Iron Diene Hydride Davis reagent |