首页 | 本学科首页   官方微博 | 高级检索  
     


Reactions of an indolinonic nitroxide with superoxide radical anion in the presence of alkylhalides. Unexpected formation of a reduced transposed product
Authors:Patricia Carloni  Roberto Vianelli  Lucedio Greci
Abstract:This study concerns the reactions of 2‐methyl‐2‐phenyl‐3‐phenylimino‐2,3‐dihydroindol‐l‐oxyl and 2,2,6,6‐tetramethylpiperidine‐1‐oxyl with alkylperoxyls, generated from potassium superoxide and a series of alkylhalides, in order to evaluate possible differences in reactivity with primary, secondary and tertiary alkylperoxyls. To better understand the reactivity of the studied indolinonic aminoxyl in alkaline medium, the investigation was extended to its reactions with potassium hydroxide and potassium tert‐butoxide in different solvents.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号