|
|||||
|
|
Indirect detection of 31P,X connectivities with proton sensitivity: application of two‐dimensional 31P‐relayed 1H,X correlation spectroscopy |
|
| Abstract: | Experiments for 1H‐detected heteronuclear 1H,X correlation spectroscopy with 31P‐relayed coherence transfer are described which allow the indirect detection of δX and nJ(X,P) even in the absence of a direct J(X,H) coupling. The use of these techniques for the assignments of 13C, 15N, and 183W NMR data of organophosphorus compounds is demonstrated. Copyright © 2003 John Wiley & Sons, Ltd. |
| Keywords: | NMR 1H NMR 31P NMR 13C NMR 15N NMR 183W NMR indirect detection heteronuclear correlation spectroscopy two‐dimensional spectroscopy |