Three-dimensional structures of phosphorus-containing heterocycles. Communication 34. 2-Phenoxy-2-oxo-1,3,2-oxathiaphosphorinanes

Conclusions According to the data from the¹H NMR spectra, the dipole moments, and the Kerr effect, the preferred conformation of 2-aroxy-2-oxy-1,3,2-oxathiaphosphorinanes is a chair conformation with an axial orientation of the aroxy grouping and a gauche orientation of the aryl group relative to the P=O bond on the side of the cyclic oxygen atom. In the investigated compounds the p- conjugation is disrupted, as evidenced by the orthogonal orientation of the unshared pair of p electrons of the exocyclic oxygen atom and the orbitals of the benzene ring.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 570–575, March, 1985.