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Dissolution of Al2O3-polystyrene latex composites: a fluorescence study
Abstract:This work reports the use of the steady state fluorescence (SSF) technique to study dissolution of a composite film formed from a mixture of Al2O3 and polystyrene (PS) latex particles. The composite films were cast from dispersion of pyrene (P)-labeled PS particles in Al2O3 solution at room temperature and annealed at 280°C temperature for 10 min. Eight different composite films were studied in various latex contents. Toluene was used as dissolution agent. Fluorescence intensities I P from P were monitored during dissolution. Fickian diffusion was employed to model the dissolution processes. Dissolution coefficients, D d, were measured and found to be increased at high PS content in the composite films.
Keywords:COMPOSITE  DISSOLUTION  FLUORESCENCE  LATEX
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