Quasi-intramolecular acid–base reactions in aqueous solutions of metal-complexes of basic ligands I. Generalized theoretical considerations on the deammoniation of [ML m ]X n type ammonia complexes |
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| Authors: | Kótai László Gács István Kazinczy Béla Sajó István E Sreedhar B |
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| Institution: | (1) Chemical Research Center, Hungarian Academy of Sciences, Institute of Chemistry, Budapest, Pusztaszeri u. 59-67, H-1025, Hungary;(2) Inorganic Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, 500 007, India |
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| Abstract: | The theoretical investigation on the distribution of chemical species obtainable as a function of the temperature of the aqueous solutions of metal complexes containing a basic ligand, altogether with the solubility relationship of the compounds to be formed, offers a simple means of planning the preparation of various types of complexes, double and single salts of the central metal cation and onium type compounds of protonated ligand of the central ion and the anion. |
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