Abstract: | Kinetic study of C2H4 polymerization on reduced V2O5/Al2O3 catalysts revealed that the rate equation can be expressed as V=k exp (-Y) KaPE/(1+KaPE) in the temperature range of –20 to 70°C. The deactivation constant, , was found to have a close relation with the yield and molecular weight of the polymer. C2H4 V2O5/Al2O3 –20 +70°C : Vp=k·exp(-Yp)·KaPe/(1+KaPe). . |