Ab initio study on far-infrared spectra of dihalodiammine complexes of palladium(II) and platinum(II). |
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| Authors: | Lin Zhang Hua Wei Yu Zhang Zijian Guo Longgen Zhu |
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| Institution: | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Jiangsu, People's Republic of China. |
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| Abstract: | The far-infrared spectra of dihalodiammine complexes of Pd(II) and Pt(II) are calculated using ab initio method at RHF/LANL2DZ level. The calculated vibrational frequencies are in good agreement with the experimental ones except for M-N stretching frequencies in cis-M(NH3)2X2 complexes, and the reason for the deviation is discussed. |
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