Isocorannulenofuran: a versatile building block for the synthesis of large buckybowls |
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| Authors: | Sygula Andrzej Sygula Renata Rabideau Peter W |
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| Institution: | Department of Chemistry, Mississippi State University, Mississippi State, MS 39762, USA. asygula@chemistry.msstate.edu |
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| Abstract: | Isocorannulenofuran, synthesized in two steps from accessible bromocorannulene, gives Diels-Alder adducts with benzynes which can be deoxygenated to produce large polycyclic aromatic hydrocarbons (PAHs) combining the bowl-shaped corannulene subunit with planar fragments. reaction: see text] |
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