Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes |
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| Authors: | Chen Zuofeng Chen Chuncheng Weinberg David R Kang Peng Concepcion Javier J Harrison Daniel P Brookhart Maurice S Meyer Thomas J |
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| Institution: | Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA. |
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| Abstract: | Electrocatalytic reduction of CO(2) by Ru(tpy)(bpy)(solvent)](2+) (tpy = 2,2':6',2'-terpyridine, bpy = 2,2'-bipyridine) and its structural analogs is initiated by sequential 1e(-) reductions at the tpy and bpy ligands followed by rate limiting CO(2) addition to give a metallocarboxylate intermediate. It undergoes further reduction and loss of CO. |
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