| 甲基丙烯酸缩水甘油酯的常温原子转移自由基活性聚合 |
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| 引用本文： | 张望清,史林启,杜满泉,尹芬芳,何炳林,高立超,高俊刚.甲基丙烯酸缩水甘油酯的常温原子转移自由基活性聚合[J].应用化学,2001,18(5):370-0. |
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| 作者姓名： | 张望清 史林启 杜满泉 尹芬芳 何炳林 高立超 高俊刚 |
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| 作者单位： | 1. 南开大学高分子研究所
2. 河北大学化学系保定 |
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| 基金项目： | 国家自然科学基金资助(59873012)和高等学校骨干教师资助计划项目 |
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| 摘 要： | 甲基丙烯酸缩水甘油酯的常温原子转移自由基活性聚合
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| 关 键 词： | 甲基丙烯酸缩水甘油酯的常温原子转移自由基活性聚合 |
| 文章编号： | 1000-0518(2001)05-0370-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2001年1月20日 |
Atom Transfer Radical
Polymerization of GMA at Room Temperature |
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| ZHANG Wang-Qing,SHI Lin-Qi,DU Man-Quan,YIN Fen-Fang,HE Bing-Lin,GAO Li-Chao,GAO Jun-gang.Atom Transfer Radical
Polymerization of GMA at Room Temperature[J].Chinese Journal of Applied Chemistry,2001,18(5):370-0. |
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| Authors: | ZHANG Wang-Qing SHI Lin-Qi DU Man-Quan YIN Fen-Fang HE Bing-Lin GAO Li-Chao GAO Jun-gang |
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| Institution: | ZHANG Wang-Qing,SHI Lin-Qi *,DU Man-Quan,YIN Fen-Fang,HE Bing-Lin |
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| Abstract: | Atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) at roomtemperature was carried out in a methylethyl ketone/1-propanol (in 7/3 volume ratio) solution,initiated and catalyzed by ethyl 2-bromopropionate (BRA)/CuC1/2,2＇ -bipyridine (BPY). Polymer ofGMA with planned molecular weight and narrow molecular weight distribution was obtained. In caseof bulk polymerization with the same initiator and catalyst the molecular weight of the polymerobtained was 1.5～2. 1 times greater than that of the above one. By using 1-phenylethyl chloride(PECl)/CuCl/BPY as catalyst controlled ATRP of GMA has failed whether it was in bulk or insolution. |
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| Keywords: | glycidyl methacrylate atom transfer radical polymerization living polymerization |
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