Thermodynamics of aqueous mixtures of nonelectrolytes. IV. Excess volumes of water-acetonitrile mixtures from 15 to 35°C |
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Authors: | Yash Paul Handa George C Benson |
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Institution: | (1) Division of Chemistry, National Research Council of Canada, K1A 0R6 Ottawa, Ontario, Canada |
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Abstract: | Excess volumes of water-acetonitrile mixtures were obtained from measurements of density over the entire mole fraction range and at 5 degree intervals from 15 to 35°C. Partial molar excess volumes at the five temperatures, excess coefficients of thermal expansion at 25°C and partial molar excess expansibilities at 25°C were derived from the results. The values of the various volumetric properties are compared with data from the literature.Issued as NRCC No. 19500 |
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Keywords: | Density acetonitrile excess volume mixture density partial molar volume thermal expansibility water-acetonitrile mixtures |
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