Abstract: | The reactions of 2-furaldehyde, 2-thiophenecarbaldehyde, and their 5-methyl derivatives with 2-aminopyridines and some other amines in the presence of molecular sieves as a dehydrating agent and acid catalyst have been studied. A series of new heterocyclic azomethines was synthesized. Proposals were made for the mechanism of the condensation involving 2-aminopyridines and the structure of the intermediates in these processes.Latvian Institute of Organic Synthesis, Riga LV-1006, Latvia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 890–897, July, 2000. |