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The sonoelectrooxidation of thiophene S-oxides
Authors:Valcarel Jesus Iniesta  Walton David J  Fujii Hideki  Thiemann Thies  Tanaka Yasuko  Mataka Shuntaro  Mason Timothy J  Lorimer J Phillip
Institution:School of Science and the Environment, Coventry University, Priory Street, Coventry CV1 5FB, UK.
Abstract:Thiophene-S-oxides (thiophene monoxides) are relatively new compounds, less stable than the better-known thiophene-S-dioxides. They are useful as synthons for a range of applications, including in the production of pharmaceuticals. They have interesting photochemical properties, but in this presentation we contrast the electro-oxidative voltammetry of differently substituted derivatives. We also compare carbocyclic compounds such as tetracyclone, the electro-oxidation of which at relatively high potentials has never been reported in silent or insonated conditions.
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