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Structural and tribological properties of cluster-assembled CNx films
Authors:M. Blomqvist  G. Bongiorno  A. Podestà  V. Serin  G. Abrasonis  U. Kreissig  W. Möller  E. Coronel  S. Wachtmeister  S. Csillag  V. Cassina  P. Piseri  P. Milani
Affiliation:1. Dipartimento di Fisica and CIMAINA, Università di Milano, Via Celoria 16, 20133, Milano, Italy
2. CEMES-CNRS, 29 rue J. Marvig, 94347, 31055, Toulouse Cedex, France
3. Institute of Ion Beam Physics and Materials Research, Forschungszentrum Dresden-Rossendorf, PF-510119, 01314, Dresden, Germany
4. The Tribomaterials Group at ?ngstr?m Laboratory, Uppsala University, Box 534, 75121, Uppsala, Sweden
5. Department of Physics, Stockholm University, SCFAB, 10691, Stockholm, Sweden
Abstract:We report the structural and tribological characterization of nanostructured CNx thin films produced by the deposition of a supersonic carbon cluster beam assisted by nitrogen ion bombardment. The influence of the deposition parameters on the chemical composition and structure of the films has been systematically studied by X-ray photoelectron spectroscopy, elastic recoil detection analysis, transmission electron microscopy and atomic force microscopy. Depending on the deposition parameters, the films show a structure ranging from amorphous to disordered graphitic with interlinked planes. Nitrogen content depends on the nitrogen ion kinetic energy. The films have a very low density with a high surface roughness. Friction measurements at the nanoscale show a correlation between nitrogen content and mechanical properties of the system. PACS 61.46-w
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