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Investigation of curing kinetics of various cycloaliphatic epoxy resins using dynamic thermal analysis
Authors:Myong Jae Yoo  Sang Hyun Kim  Woo Sung Lee  Jae-Hong Choi
Affiliation:a Electronic Materials & Device Research Center, Korea Electronics Technology Institute, Seongnam 463-816, Republic of Korea
b Department of Materials Science and Engineering, Korea University, Seoul 136-701, Republic of Korea
Abstract:Curing reactions of three cycloaliphatic epoxy resins with methyltetrahydrophthalic anhydride (MTHPA) was investigated by differential scanning calorimetry at different heating rates. Activation energy was calculated based on Kissinger method and varied in the range of 67-72 kJ/mol depending on sample. The curing kinetic behavior was well described by Sestak-Berggren (SB) model and the order of the curing reaction is observed to be from 0.02 to 2.11 according to sample.
Keywords:Cure kinetics   Cycloaliphatic epoxy resin   Differential scanning calorimetry   Activation energy
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