| Crystal Structure and EPR Spectra of cis—Dioxo—molybdenum（V） Complex with o—Aminophenol |
| |
| 引用本文： | 鲁晓明,卢景芬,等.Crystal Structure and EPR Spectra of cis—Dioxo—molybdenum（V） Complex with o—Aminophenol[J].中国化学,2002,20(6):617-621. |
| |
| 作者姓名： | 鲁晓明 卢景芬 |
| |
| 作者单位： | [1]WuhanInstituteofPhysicsandMathematics,ChineseAcademyofScience,Wuhan430071,China [2]StateKeyLaboratoryofNaturalandBiomimeticDrugs,MedicineScienceCenter,PekingUniversity,Beijing100083, |
| |
| 基金项目： | theNaturalScienceFoundationofBeijingProvince (No .2 0 12 0 0 5 )，theNaturalScienceFoundationofEduca tionalMinistryofBeijing |
| |
| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＭｏｌｙｂｄｅｎｕｍｉｓｗｉｄｅｌｙｕｓｅｄｉｎｂｉｏｌｏｇｉｃａｌｓｙｓｔｅｍｓｄｕｅｔｏｔｈｅｔｗｏｂａｓｉｃｆｏｒｍｓ :ｎｉｔｒｏｇｅｎａｓｅｓａｎｄｏｘｏｔｒａｎｓｆｅｒａｓｅｓｏｒｏｘｏｍｏｌｙｂｄｏｅｎｚｙｍｅｓ .Ｔｈｅｌａｔｔｅｒａｓｔｈｅｍｏｎｏｎｕｃｌｅａｒａｃｔｉｖｅｓｉｔｅｓｏｆａｍｕｃｈｍｏｒｅｄｉｖｅｒｓｅｇｒｏｕｐｏｆｅｎｚｙｍｅｓｉｎｇｅｎｅｒａｌｆｕｎｃｔｉｏｎｃａｔａｌｙｔｉｃａｌｌｙｔｒａｎｓｆｅｒａｎｏｘｙｇｅｎａｔｏｍｅｉｔｈｅｒｔ…
|
| 关 键 词： | 钼（V） 配合物 合成 EPR 晶体结构 氨基苯酚 |
Crystal Structure and EPR Spectra of cis-Dioxo-molybdenum(V) Complex with o-Aminophenol |
| |
| LU,Xiao Ming LU,Jing Fen MAO,Xi An a Wuhan Institute of Physics and Mathematics,Chinese Academy of Science,Wuhan ,China b.Crystal Structure and EPR Spectra of cis-Dioxo-molybdenum(V) Complex with o-Aminophenol[J].Chinese Journal of Chemistry,2002,20(6):617-621. |
| |
| Authors: | LU Xiao Ming LU Jing Fen MAO Xi An a Wuhan Institute of Physics and Mathematics Chinese Academy of Science Wuhan China b |
| |
| Institution: | LU,Xiao Ming LU,Jing Fen MAO,Xi An a Wuhan Institute of Physics and Mathematics,Chinese Academy of Science,Wuhan 430071,China b Department of Chemistry,Capital Normal University,Beijing 100037,China cState Key Laboratory |
| |
| Abstract: | The paramagnetic cis‐dioxo‐molybdenum(V) complex, NH2CH2CH2NH3]3MovO2(HNC6H4O)2] was obtained by the reaction of tetra‐butyl ammonium β‐octamolybdate with o‐aminophenol and ethylenediamine in the mixed solvent of CH3OH and CH3CN, and characterized by IR, NMR, EPR spectroscopy and X‐ray diffraction analysis. The determination of single crystal X‐ray analysis revealed that the central Mov ion metal center exhibits distorted octahedral coordination with cis‐dioxo o‐aminophenol. The EPR spectra of both the complex and flavoenzyme show similarly. Thus it suggests that the complex anion MovO2(HNC6H4O)2]3‐ and flavoenzyme have related structure feature. |
| |
| Keywords: | cis dioxo molybdenum(V) complex anion o amino~phenol oxomolybdoenzyme X ray crystallography EPR spectra |
| 本文献已被 CNKI 维普 等数据库收录！ |
