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Palladium-catalyzed heck arylations of allyl alcohols in ionic liquids: remarkable base effect on the selectivity
Authors:Calò Vincenzo  Nacci Angelo  Monopoli Antonio  Ferola Valentina
Institution:CNR - ICCOM, Department of Chemistry, University of Bari, Via Orabona 4, 70126-Bari, Italy.
Abstract:Pd-catalyzed Heck arylation of allyl alcohols in tetraalkylammonium ionic liquids (ILs) can be made highly selective toward the formation of either aromatic carbonyl compounds or aromatic conjugated alcohols by carefully choosing both the IL and the base.
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