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Urethane N-carboxyanhydrides from beta-amino acids
Authors:McKiernan M  Huck J  Fehrentz J A  Roumestant M L  Viallefont P  Martinez J
Institution:UMR 5810-CNRS, LAPP Universités Montpellier I et II, Place Eugène Bataillon, 34095 Montpellier Cedex 5, France.
Abstract:A general method has been developed for the synthesis of N-tert-butyloxycarbonyl N-carboxyanhydrides from beta-amino acids using Vilsmeier complex. These beta-UNCA are stable, and the reactivity with different nucleophiles (alcohol, amine, lithium enolate) was studied.
Keywords:
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