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Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex
Authors:Potekhin  V V  Solov'eva  S N  Potekhin  V M
Institution:1. St. Petersburg State Institute of Technology, St. Petersburg, Russia
Abstract:The catalytic oxidation of iron(II) with oxygen occurs along with an autocatalytic reaction between palladium(II) tetraaqua complex and iron(II) aqua complex in an oxygen atmosphere. The reaction is catalyzed by a compound of palladium in an intermediate oxidation state, presumably by a small palladium cluster formed in the course of the reduction of palladium(II) tetraaqua complex with iron(II) aqua complex.
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