Catalytic Oxidation of Iron(II) Aqua Complex by Oxygen in the Presence of Palladium(II) Tetraaqua Complex |
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Authors: | Potekhin V V Solov'eva S N Potekhin V M |
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Institution: | 1. St. Petersburg State Institute of Technology, St. Petersburg, Russia
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Abstract: | The catalytic oxidation of iron(II) with oxygen occurs along with an autocatalytic reaction between palladium(II) tetraaqua complex and iron(II) aqua complex in an oxygen atmosphere. The reaction is catalyzed by a compound of palladium in an intermediate oxidation state, presumably by a small palladium cluster formed in the course of the reduction of palladium(II) tetraaqua complex with iron(II) aqua complex. |
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