First structural characterization of neutral, base-stabilized group 15-pentaazides: single crystal X-ray structures of dmap-As(N3)5 and dmap-Sb(N3)5 |
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| Authors: | Lyhs Benjamin Bläser Dieter Wölper Christoph Schulz Stephan Jansen Georg |
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| Affiliation: | Chemistry Department, University of Duisburg-Essen, Universit?tsstrasse 5-7, D-45117 Essen, Germany. |
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| Abstract: | Two neutral group 15-pentaazides dmap-As(N(3))(5) (1) and dmap-Sb(N(3))(5) (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides. |
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