Reactivity of phosphonodithioato-dppt Ni(II) mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion |
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| Authors: | Aragoni M Carla Arca Massimiliano Coles Susanne L Devillanova Francesco A Hursthouse Michael B Isaia Francesco Lippolis Vito |
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| Affiliation: | Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Cittadella Universitaria Monserrato, 09042 Cagliari, Italy. aragoni@unica.it |
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| Abstract: | The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes. |
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