Deca-heterosubstituted corannulenes |
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| Authors: | Pogoreltsev Alla Solel Ephrath Pappo Doron Keinan Ehud |
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| Institution: | Schulich Faculty of Chemistry, Technion - Israel Institute of Technology, Technion City, Haifa 32000, Israel. |
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| Abstract: | The Cu(I)-catalyzed Ullmann condensation reaction between aliphatic alcohols and sym-pentachlorocorannulene provides a convenient entry to 1,3,5,7,9-pentaalkoxycorannulenes. The latter are easily converted to novel deca-heterosubstituted derivatives, such as 1,3,5,7,9-penta-X-2,4,6,8,10-penta-Y-corannulenes by electrophilic aromatic substitution. |
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