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Topological ferroelectric bistability in a polarization-modulated orthogonal smectic liquid crystal
Authors:Zhu Chenhui  Shao Renfan  Reddy R Amaranatha  Chen Dong  Shen Yongqiang  Gong Tao  Glaser Matthew A  Korblova Eva  Rudquist Per  Maclennan Joseph E  Walba David M  Clark Noel A
Affiliation:Department of Physics and Liquid Crystal Materials Research Center, University of Colorado, Boulder, Colorado 80309, USA.
Abstract:We report a bent-core liquid crystal (LC) compound exhibiting two fluid smectic phases in which two-dimensional, polar, orthorhombic layers order into three-dimensional ferroelectric states. The lower-temperature phase has a uniform polarization field which responds in an analog fashion to applied electric field. The higher-temperature phase is a new smectic state with periodic undulation of the polarization, structurally modulated layers, and a bistable response to applied electric field which originates in the periodically splay-modulated bulk of the LC rather than by surface stabilization at the cell boundaries.
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