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Is the decomposition of the primary ozonide a concerted or stepwise process?
Authors:P.C. Hiberty  J.P. Devidal
Abstract:An ab initio SCF-MO calculation shows that both concerted and stepwise processes are equally probable for the cleavage of the primary ozonide, leading to the Criegee intermediate. The value of the corresponding activation energy is discussed, and the results are found in agreement with the stereochemistry of the reaction. A very facile ring opening is also predicted.
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