The reaction of 2,5-bis(diethylaminomethyl)-hydroquinone with di- and trialkyl phosphites |
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| Authors: | B E Ivanov L A Valitova V I Gaidai T G Bykova N I Kuchma S V Samurina |
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| Institution: | 1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Branch, Academy of Sciences of the USSR, USSR
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| Abstract: | | 1. |
An intermediate alkoxyphosphorane with two pentacoordinated phosphorus atoms was isolated and characterized during the reaction of 2,5-bis(diethylaminomethyl)hydroquinone with trialkyl phosphites.
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A method has been developed for the synthesis of phosphorylated dihydric phenols.
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The triethylether of 3-ethoxy-6-hydroxy-1,4-xylyenediphosphonic acid was prepared by the interaction of 2,5-bis(diethylaminomethyl)hydroquinone with diethylphosphorous acid in the presence of triethyl phosphite.
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