Preparation of Perfluoroalkyl Substituted Saccharides and Their Distribution Ratio between Organic and Fluorous Sovlents |
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Authors: | LI Bing YU Biao HUI Yong-Zheng MA Xing-Quan |
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Institution: | Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032 |
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Abstract: | A "fluorous synthesis" approach is outlined in which organic molecules are rendered solublity in fluorocarbon solvents by attachment of a suitable fluorocanbon group. Fluorocarbon sovlents are immisicible in organic solutions, and fluorous molecules partition out of an organic phanse and into a fluorous phase in a standard liquid-liquid extraction. Simple yet substantive separations of organic reaction mixtures are achieved without resorting to chromatography. This methed has been used in many fields, but seldom in oligosacchride synthesis. |
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