One-dimensional infinite chain crown ether complex:Synthesis and crystal structure of[Na(18C6)]2[Cu(mnt)2]·H2O |
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| Authors: | DOU Jian-Min LI Da-Cheng LIU Ying XU Li-Qiang BI Wen-Hua |
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| Institution: | Department of Chemistry, Liaocheng Teacher's University, Liaocheng, 252000 |
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| Abstract: | One-dimensional coordination polymers have attracted considerable interest in recent years because of the prospect of electrical, optical and magnetic properties. Crown ether can form one-dimensional infinite chain structure with transition metal complex. We synthesized the complexes of 18-crown-6 with Na2m{S2C2(CN)2}2](m=Cu, Ni, Pd, Pt; S2C2(CN)22- mnt) and now report the structure of complexNa(18C6)]2Cu(mnt)2]·H2O. |
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