Synthesis and Crystal Structure of Molybdenum-Sulfur Cluster Compounds Coordinated by Nicotinic Acid and Isonicotinic Acid |
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| Authors: | QIN Ye-Yan WU Ling TANG Yan-Hong KANG Yao LI Zhao-Ji YAO Yuan-Gen |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou 350002 |
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| Abstract: | Cuboidal Molybdenum have been paid much attention due to their structural resemble with those metallic centers in some biological systems[1]. To explore the chemistry of trinuclear Mo-S cluster complexes[2], we rationally synthesized two compounds:Mo3S4(DTP)3(nicotinate)(Py)·EtOH (Ⅰ) (DTP=diethyl dithiophosphate) and Mo3S4(DTP)3(isonicotinate)(Py)·EtOH (Ⅱ) by the substitution reaction of Mo3S4(DTP)3(L)(Py) (L=ClCH2COO-, CH3COO-) with nicotinic acid and isonicotinic acid, respectively. |
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