Simulation of initiated nonbranched chain oxidation of hydrogen: Oxygen as an autoinhibitor |
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Authors: | M M Silaev |
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Institution: | (1) Moscow State University, Leninskie gory, Moscow, 119991, Russia |
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Abstract: | A simple kinetic equation describing nonmonotonic (with a maximum) dependence of the hydrogen peroxide and water formation rate on the oxygen concentration was derived by the quasi-steady-state treatment in terms of the nonbranched-chain free-radical mechanism of noncatalytic hydrogen oxidation involving the relatively low-reactive radical HO 4 ? , which inhibits the chain process. Possible nonchain pathways of the free-radical oxidation of hydrogen, the energetics of key radical-molecule reactions, and the routes of ozone decay from the energetics standpoint via the reaction with the HO? radical in the upper atmosphere (including the addition yielding the HO 4 ? radical, which can be an intermediate in the sequence of conversions of biologically hazardous UV radiation energy) were considered. |
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