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Selective recognition of Ca ions using novel polymeric phenols
Authors:Sunil K. Sharma  Sumit Kumar  Eugene F. Barry  Arthur C. Watterson  Virinder S. Parmar
Affiliation:a Bioorganic Laboratory, Department of Chemistry, University of Delhi, Delhi 110 007, India
b Institute for Nano-Science and Engineering Technology, Department of Chemistry, University of Massachusetts, Lowell, MA 01854, United States
Abstract:The research described here elucidates the fundamental interactions of various cations with phenolic moieties constituting the side chains of novel copolymers. The phenolic group was chosen because similar interactions of the tyrosine (Tyr) moiety in proteins with alkaline earth cations are of particular interest for some biochemical systems where both the alkaline earth cations and the aromatic compounds are abundant. The present study has revealed the preferred binding site for our polymeric systems.
Keywords:Tyr, Tyrosine   DNA, Deoxyribose nucleic acid   RNA, Ribose nucleic acid   PEG, Polyethylene glycol   UV, Ultraviolet   PD, Polydispersity
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