Mechanism of Formation of Tetrahydrofuran in the Catalytic Hydrogenation of Dialkyl Succinates |
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| Authors: | A F Timofeev A G Bazanov N G Zubritskaya |
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| Institution: | 1.“Applied Chemistry” Russian Research Center,St. Petersburg,Russia |
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| Abstract: | The kinetics of formation of tetrahydrofuran from dibutyl succinate were studied. The mechanism of catalytic hydrogenation of dialkyl succinates was found to involve consecutive formation of ?-butyrolactone, butane-1,4-diol, and tetrahydrofuran. Parameters of kinetic equations that properly describe the system of concurrent and consecutive reactions were determined. |
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