Configurational stability in some 3-coordinate phosphorus compounds |
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| Authors: | B. Fontal and H. Goldwhite |
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| Affiliation: | Department of Chemistry, California State College at Los Angeles, Los Angeles, California 90032 U.S.A. |
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| Abstract: | PMR spectra of a variety of 4,4,5,5-tetramethyl-1,3,2-dioxaphospholanes, bearing different substituents at phosphorus, have been determined at different temperatures. There is no inversion at phosphorus detectable. The P-chloro compound undergoes a chemical exchange process the rate of which is concentration dependent. |
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