| 有机硅聚丙烯酸酯微乳液的合成与性能 |
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| 引用本文： | 张臣,张力,李国明. 有机硅聚丙烯酸酯微乳液的合成与性能[J]. 应用化学, 2004, 21(2): 182-0 |
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| 作者姓名： | 张臣 张力 李国明 |
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| 作者单位： | 华南师范大学 |
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| 基金项目： | 广东省科委重点攻关项目 ( 2KM0 62 0 2S)，广州市高新技术 ( 2 0 0 0 Z 0 86 0 1)资助项目 |
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| 摘 要： | 有机硅聚丙烯酸酯微乳液的合成与性能;硅氧烷
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| 关 键 词： | 有机硅聚丙烯酸酯微乳液的合成与性能 硅氧烷 |
| 文章编号： | 1000-0518(2004)02-0182-05 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2003-05-15 |
Synthesis of Poly(siloxane-acrylate) Microemulsion and Its Property |
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| ZHANG Chen,ZHANG Li ,LI Guo-Ming. Synthesis of Poly(siloxane-acrylate) Microemulsion and Its Property[J]. Chinese Journal of Applied Chemistry, 2004, 21(2): 182-0 |
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| Authors: | ZHANG Chen ZHANG Li LI Guo-Ming |
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| Affiliation: | ZHANG Chen,ZHANG Li *,LI Guo-Ming |
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| Abstract: | The poly(siloxane-acrylate) microemulsions were synthesized using K 2S 2O 8 as initiator and copolymer nanoparticles were obtained. The effects of polymerization methods, the TS/SDS mass ratio and the content of siloxane on the polymerization and properties of the microemulsion were investigated. The best results were obtained by seeding semi-continuous emulsion polymerization, by which the poly(siloxane-acrylate) microemulsion with average particle size of 46.1 nm could be obtained with low surfactant concentration(2.5%) and relatively high copolymer content(30%). |
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| Keywords: | siloxane acrylates copolymer microemulsion synthesis |
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