| 二维纳米空洞方格:诺氟沙星锰(Ⅱ)配合物 |
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| 引用本文： | 王立中,陈振锋,王锡森,李咏华,熊仁根,游效曾. 二维纳米空洞方格:诺氟沙星锰(Ⅱ)配合物[J]. 无机化学学报, 2002, 18(12): 1185-1190 |
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| 作者姓名： | 王立中 陈振锋 王锡森 李咏华 熊仁根 游效曾 |
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| 作者单位： | 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家重点基础研究发展规划资助项目(G2000077500)，国家自然科学基金资助项目，教育部优秀青年教师资助计划项目 |
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| 摘 要： | The reactions of norfloxacin (H-Norf) with Mn(ClO4)2·6H2O and Mn(OH)2 yield Mn(H-Norf)(ClO4)2·2H2O (1) and [Mn(Norf)2·4H2O]n (2) , respectively. 1 is monomeric while 2 has a novel 2D neutral square grid with an antibacterial drug as building block. Crystal data for 1: triclinic, space group P1 (No.2), a=9.0939(3), b=9.4395(3), c=12.7182(3)?, α=111.447(2), β=90.340(2), γ=112.357(1)°, V=926.34(5)?3, Z=1, ρcacl=1.664g·cm-3. MoKα radiation (λ=0.71073?), T=293(2)K, μ=0.595mm-1, R1=0.0692, wR2=0.1482 for 2320 observed reflections from 4390 independent reflections, GOF=0.940; Crystal data for 2: Monoclinic, P21/c, a=5.7530(12), b=21.865(4), c=13.343(3)?, β=98.25(3)°, V=1661.1(6)?3, Z=2, ρcacl=1.527g·cm-3, T=293(2)K, μ=0.477mm-1, R1=0.0531, wR2=0.1552 for 2070 observed reflections from 2870 independent reflections, GOF=1.384. CCDC: 140819; 151063.
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| 关 键 词： | 纳米空洞 诺氟沙星 锰(Ⅱ)配合物 |
2D Nanoporous Molecular Square Grid: Manganese (Ⅱ) Norfloxacin Complex |
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| WANG Li-Zhong,CHEN Zhen-Feng,WANG Xi-Sen,LI Yong-Hu,XIONG Ren-Gen and YOU Xiao-Zeng. 2D Nanoporous Molecular Square Grid: Manganese (Ⅱ) Norfloxacin Complex[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(12): 1185-1190 |
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| Authors: | WANG Li-Zhong CHEN Zhen-Feng WANG Xi-Sen LI Yong-Hu XIONG Ren-Gen YOU Xiao-Zeng |
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| Affiliation: | Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | The reactions of norfloxacin (H-Norf) with Mn(ClO4) 2 @ 6H2O and Mn(OH) 2 yield Mn(H-Norf) (ClO4) 2 @2H2O (1) and [Mn(Norf)2 @ 4H2O]n (2) , respectively. 1 is monomeric while 2 has a novel 2D neutral square grid with an antibacterial drug as building block. Crystal data for 1: triclinic, space group P1 (No. 2), a = 9.0939(3), b=9.4395(3), c=12.7182(3)A, α=111.447(2), β=90.340(2), γ=112.357(1)°, V=926.34(5)A3, Z=1, ρcacl=1. 664g@ cm-3. MoKα radiation (λ=0.71073A), T=293(2) K, μ=0.595mm-1, R1=0. 0692, w R2 = 0. 1482 for 2320 observed reflections from 4390 independent reflections, GOF = 0. 940; Crystal data for2: Monoclinic, P21/c, a=5.7530(12), b=21.865(4), c=13.343(3) A, β=98.25(3)°, V=1661.1(6) A3, Z=2, ρcacl=1.527g@cm-3, T=293(2) K, μ=0.477mm-1, R1=0.0531, wR2=0.1552 for 2070 observed reflections from 2870 independent reflections, GOF = 1. 384. CCDC: 140819; 151063. |
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| Keywords: | nanoporous norfloxacin manganese complex |
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