Palladium(<Emphasis Type="SmallCaps">I</Emphasis>) and palladium(0) carbonyl bromide complexes |
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| Authors: | A V Kulik O N Temkin L G Bruk V E Zavodnik V K Belsky V V Minin |
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| Institution: | (1) M. V. Lomonosov Moscow State Academy of Fine Chemical Technology, 86 prosp. Vernadskogo, 119571 Moscow, Russian Federation;(2) L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 105064 Moscow, Russian Federation;(3) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | New PdI and Pd0 carbonyl bromide complexes co-existing in the same crystal were synthesized and studied by X-ray diffraction analysis. The
crystals consist of dimeric complex anions composed of the central Pd(μ-CO)2Pd fragment and four partially disordered terminal ligands (CO and Br−). The complexes were characterized by IR, ESR, and X-ray photoelectron spectroscopy.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1349–1355, June, 2005. |
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| Keywords: | palladium carbonyl complexes palladium(0) I)" target="_blank">palladium(I) palladium bromide complexes |
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