| STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE |
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| 作者姓名： | Jia Sheng GUO Xiao Tian LIANG |
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| 作者单位： | Institute of Materia Medica Chinese Academy of Medical Sciences, Beijing 100050 |
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| 摘 要： | The configuration of the hydroxy acid 2, a product from base-catalyzedautoxidation of 3α,5-cyclo-5α-cholestane-6-one,was established on the basis of NMRtechniques and the mechanism of the formation of 2 was discussed.
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STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE |
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| Jia Sheng GUO,Xiao Tian LIANG.STEREOCHEMISTRY OF THE BENZILIC ACID-TYPE REARRANGEMENT IN BASE-CATALYZED AUTOXIDATION OF 3α,5-CYCLO-5α-CHOLESTANE-6-ONE[J].Chinese Chemical Letters,1991,2(3):189-190. |
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| Authors: | Jia Sheng GUO Xiao Tian LIANG |
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| Institution: | Institute of Materia Medica Chinese Academy of Medical Sciences, Beijing 100050 |
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| Abstract: | The configuration of the hydroxy acid 2, a product from base-catalyzed autoxidation of 3α, 5-cyclo-5α-cholestane-6-one, was established on the basis of NMR techniques and the mechanism of the formation of 2 was discussed. |
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