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CHARACTERIZATIONS ON THE THIXOTROPY-LOOP TESTS USING UCM MODEL WITH A RATE-TYPE KINETIC EQUATION
作者姓名:Shu-xin  Huang  and  Chuan-jing  Lu
作者单位:Shu-xin Huang and Chuan-jing Lu Department of Engineering Mechanics,Shanghai Jiao Tong University,Shanghai 200030,China
摘    要:The theoretical characterizations on the triangular-form thixotropy-loop tests of an LDPE melt (PE-FSB-23D022/Q200) were conducted in the present paper by using a new thixotropy model, which is constituted by the upper convected Maxwell model and a rate-type kinetic equation. The new thixotropic Maxwell model can partially describe well three reported thixotropy-loop experiments by comparison with the previous calculations of the variant form of the thixotropy-type Huang model. It is noted that the stress deviations between the experiments and the predictions of the new thixotropic Maxwell model are much slighter than those deviations obtained by using the variant Huang model at the same condition, although both models include five parameters. The constitution of the new thixotropic Maxwell model is more reasonable than that of the variant Huang model.

收稿时间:2006-01-09
修稿时间:2006-02-20

CHARACTERIZATIONS ON THE THIXOTROPY-LOOP TESTS USING UCM MODEL WITH A RATE-TYPE KINETIC EQUATION
Shu-xin Huang and Chuan-jing Lu.CHARACTERIZATIONS ON THE THIXOTROPY-LOOP TESTS USING UCM MODEL WITH A RATE-TYPE KINETIC EQUATION[J].Chinese Journal of Polymer Science,2006,0(6):609-617.
Authors:Shu-xin Huang  Chuan-jing Lu
Institution:Department of Engineering Mechanics, Shanghai Jiao Tong University, Shanghai 200030, China
Abstract:The theoretical characterizations on the triangular-form thixotropy-loop tests of an LDPE melt (PE-FSB23D022/Q200) were conducted in the present paper by using a new thixotropy model, which is constituted by the upper convected Maxwell model and a rate-type kinetic equation. The new thixotropic Maxwell model can partially describe well three reported thixotropy-loop experiments by comparison with the previous calculations of the variant form of the thixotropy-type Huang model. It is noted that the stress deviations between the experiments and the predictions of the new thixotropic Maxwell model are much slighter than those deviations obtained by using the variant Huang model at the same condition, although both models include five parameters. The constitution of the new thixotropic Maxwell model is more reasonable than that of the variant Huang model.
Keywords:Thixotropy-loop tests  Theoretical characterization  Thixotropy models  KINETIC EQUATION  constitution  reasonable  models  parameters  stress  deviations  condition  thixotropic  experiments  comparison  variant  form  Huang  upper  Maxwell model  kinetic equation  present  paper  thixotropy
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