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Oxidation of pentafluoro-N-(2,3,4,5,6-pentafluorobenzylidene) aniline
Authors:N I Petrenko  T N Gerasimova
Institution:(1) Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR
Abstract:Conclusions The reaction of pentafluoro-N-(2,3,4,5,6-pentafluorobenzylidene) aniline with peracetlc acid or 90% hydrogen peroxide in CH2Cl2 at acd20°C yields agr-pentafluoroanilino-2,3,4,5,6-pentafluorobenzylhydroperoxide. Its capability for thermal and photolytic transformation into bis (agr-pentafluoroanilino-2,3,4,5,6-pentafluorobenzyl) peroxide was shown.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 665–668, March, 1985.
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